Quantum coherent biomolecular energy transfer with spatially correlated fluctuations

We show that the quantum coherent transfer of excitations between biomolecular chromophores is strongly influenced by spatial correlations of the environmental fluctuations. The latter are due either to propagating environmental modes or to local fluctuations with a finite localization length. A simple toy model of a single donor-acceptor pair with spatially separated chromophore sites allows to investigate the influence of these spatial correlations on the quantum coherent excitation transfer. The sound velocity of the solvent determines the wave lengths of the environmental modes, which, in turn, has to be compared to the spatial distance of the chromophore sites. When the wave length exceeds the distance between donor and acceptor site, we find strong suppression of decoherence. In addition, we consider two spatially separated donor-acceptor pairs under the influence of propagating environmental modes. Depending on their wave lengths fixed by the sound velocity of the solvent material, the spatial range of correlations may extend over typical interpair distances, which can lead to an increase of the decohering influence of the solvent. Surprisingly, this effect is counteracted by increasing temperature

Ceramic composites for rocket engine turbines

The use of ceramic materials in the hot section of the fuel turbopump of advanced reusable rocket engines promises increased performance and payload capability, improved component life and economics, and greater design flexibility. Severe thermal transients present during operation of the Space Shuttle Main Engine (SSME), push metallic components to the limit of their capabilities. Future engine requirements might be even more severe. In phase one of this two-phase program, performance benefits were quantified and continuous fiber reinforced ceramic matrix composite components demonstrated a potential to survive the hostile environment of an advanced rocket engine turbopump

Impact of LSP Character on Slepton Reach at the LHC

Searches for supersymmetry at the Large Hadron Collider (LHC) have significantly constrained the parameter space associated with colored superpartners, whereas the constraints on color-singlet superpartners are considerably less severe. In this study, we investigate the dependence of slepton decay branching fractions on the nature of the lightest supersymmetric particle (LSP). In particular, in the Higgsino-like LSP scenarios, both decay branching fractions of $\tilde\ell_L$ and $\tilde\nu_\ell$ depend strongly on the sign and value of $M_1/M_2$, which has strong implications for the reach of dilepton plus MET searches for slepton pair production. We extend the experimental results for same flavor, opposite sign dilepton plus MET searches at the 8 TeV LHC to various LSP scenarios. We find that the LHC bounds on sleptons are strongly enhanced for a non-Bino-like LSP: the 95% C.L. limit for $m_{\tilde\ell_L}$ extends from 300 GeV for a Bino-like LSP to about 370 GeV for a Wino-like LSP. The bound for $\tilde\ell_L$ with a Higgsino-like LSP is the strongest (~ 490 GeV) for $M_1/M_2$ ~ $-\tan^2\theta_W$ and is the weakest (~ 220 GeV) for $M_1/M_2$ ~ $\tan^2\theta_W$. We also calculate prospective slepton search reaches at the 14 TeV LHC. With 100 fb$^{-1}$ integrated luminosity, the projected 95% C.L. mass reach for the left-handed slepton varies from 550 (670) GeV for a Bino-like (Wino-like) LSP to 900 (390) GeV for a Higgsino-like LSP under the most optimistic (pessimistic) scenario. The reach for the right-handed slepton is about 440 GeV. The corresponding 5$\sigma$ discovery sensitivity is about 100 GeV smaller. For 300 fb$^{-1}$ integrated luminosity, the reach is about 50 - 100 GeV higher.Comment: 24 pages, 10 figure

Topic Development in the Freshman Engineering Paper: Finding a Focus

Topic development and focus are relatively neglected areas of the student research process. This study examined how students in a freshman engineering writing class developed initial research paper topics into focused thesis statements. A mixed methods approach was used, incorporating online surveys, qualitative interviews, and a rubric to track topic development and assess thesis statement focus. The survey results and student comments indicated that participants were more competent at the mechanics of finding sources and writing than at developing appropriately scoped thesis statements. Closer collaboration between writing instructors and librarians is urged to more effectively support and scaffold topic development

Detail design specification for enhancement of the automatic status and tracking system software

There are no author-identified significant results in this report

Preliminary design specification for the LANDSAT Imagery Verification and Extraction System (LIVES)

There are no author-identified significant results in this report

Oxygen Compatibility Screening Tests in Oxygen-Rich Combustion Environment

The identification and characterization of oxygen-rich compatible materials enables full-flow, staged combustion designs. Although these oxygen-rich designs offer significant cost, performance, and reliability benefits over existing systems, they have never been used operationally by the United States. If these systems are to be realized, it is critical to understand the long-term oxidative stability in high-temperature, high-pressure, oxygen-rich combustion environments. A unique facility has been constructed at the NASA Lewis Research Center to conduct tests of small-scale rocket engine materials and subcomponents in an oxygen-rich combustion environment that closely approximates a full-scale rocket engine. Thus, a broad range of advanced materials and concepts can be screened in a timely manner and at a relatively low cost

Effect of hydrogen on the strength and microstructure of selected ceramics

Ceramics in monolithic form and as composite constituents in the form of fibers, matrices, and coatings are currently being considered for a variety of high-temperature applications in aeronautics and space. Many of these applications involve exposure to a hydrogen-containing environment. The compatibility of selected ceramics in gaseous high-temperature hydrogen is assessed. Environmental stability regimes for the long term use of ceramic materials are defined by the parameters of temperature, pressure, and moisture content. Thermodynamically predicted reactions between hydrogen and several monolithic ceramics are compared with actual performance in a controlled environment. Morphology of hydrogen attack and the corresponding strength degradation is reported for silicon carbide, silicon nitride, alumina, magnesia, and mullite

Comparative study of theoretical methods for nonequilibrium quantum transport

We present a detailed comparison of three different methods designed to tackle nonequilibrium quantum transport, namely the functional renormalization group (fRG), the time-dependent density matrix renormalization group (tDMRG), and the iterative summation of real-time path integrals (ISPI). For the nonequilibrium single-impurity Anderson model (including a Zeeman term at the impurity site), we demonstrate that the three methods are in quantitative agreement over a wide range of parameters at the particle-hole symmetric point as well as in the mixed-valence regime. We further compare these techniques with two quantum Monte Carlo approaches and the time-dependent numerical renormalization group method.Comment: 19 pages, 7 figures; published versio

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamic maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of Region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicon carbide is the single stable solid phase in Region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4, and SiH. Analysis of the kinetics of reaction for Region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to Regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer